Prussian blue

Sample of prussian blue
Ferric ferrocyanide
Ferric hexacyanoferrate
Iron(III) ferrocyanide
Iron(III) hexacyanoferrate(II)

Sodium ferrocyanide

Prussian blue is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the idealized chemical formula Fe
7
(CN)
18
. Another name for the color is Berlin blue or, in painting, Parisian or Paris blue. Turnbull's blue is the same substance, but is made from different reagents, and its slightly different color stems from different impurities.

Prussian blue was the first modern synthetic pigment. It is prepared as a very fine colloidal dispersion, because the compound is not soluble in water. It contains variable amounts of other ions and its appearance depends sensitively on the size of the colloidal particles. The pigment is used in paints, and it is the traditional "blue" in blueprints and aizuri-e Japanese woodblock prints.

In medicine, orally administered Prussian blue is used as an antidote for certain kinds of heavy metal poisoning, e.g., by thallium and radioactive isotopes of caesium. In particular, it was used to absorb 137
Cs+
from those poisoned in the Goiânia accident. The therapy exploits the compound's ion-exchange properties and high affinity for certain "soft" metal cations.

It is on the World Health Organization's List of Essential Medicines, the most important medications needed in a basic health system. Prussian blue lent its name to prussic acid (hydrogen cyanide) derived from it. In German, hydrogen cyanide is called Blausäure ("blue acid"). French chemist Joseph Louis Gay-Lussac gave cyanide its name, from the Greek word κυανός (kyanos, "blue"), because of the color of Prussian blue.

This page was last edited on 6 May 2018, at 14:55 (UTC).
Reference: https://en.wikipedia.org/wiki/Prussian_blue under CC BY-SA license.

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