Prussian blue

Sample of prussian blue
Ferric ferrocyanide
Ferric hexacyanoferrate
Iron(III) ferrocyanide
Iron(III) hexacyanoferrate(II)

Sodium ferrocyanide

Prussian blue is a dark blue pigment with the idealized chemical formula Fe
. To better indicate the structure of this complex compound the formula can also be written as Fe

· xH
. Another name for the color is Berlin blue or, in painting, Parisian or Paris blue. Turnbull's blue is the same substance, but is made from different reagents, and its slightly different color stems from different impurities.

Prussian blue was the first modern synthetic pigment. It is prepared as a very fine colloidal dispersion, because the compound is not soluble in water. It contains variable amounts of other ions and its appearance depends sensitively on the size of the colloidal particles. The pigment is used in paints, and it is the traditional "blue" in blueprints and aizuri-e Japanese woodblock prints.

In medicine, Prussian blue is used as an antidote for certain kinds of heavy metal poisoning, e.g., by thallium and radioactive isotopes of caesium. In particular, it was used to absorb 137
from those poisoned in the Goiânia accident. Prussian blue is orally administered. The therapy exploits Prussian blue's ion-exchange properties and high affinity for certain "soft" metal cations.

It is on the World Health Organization's List of Essential Medicines, the most important medications needed in a basic health system. Prussian blue lent its name to prussic acid (hydrogen cyanide), which was derived from it. In German, hydrogen cyanide is called Blausäure ("blue acid"), and Joseph Louis Gay-Lussac gave cyanide its name, from the Greek word κυανός (kyanos, "blue"), because of the color of Prussian blue.

This page was last edited on 9 March 2018, at 16:58.
Reference: under CC BY-SA license.

Related Topics

Recently Viewed