Chlorite group

The chlorites are a group of phyllosilicate minerals. Chlorites can be described by the following four endmembers based on their chemistry via substitution of the following four elements in the silicate lattice; Mg, Fe, Ni, and Mn.

In addition, zinc, lithium, and calcium species are known. The great range in composition results in considerable variation in physical, optical, and X-ray properties. Similarly, the range of chemical composition allows chlorite group minerals to exist over a wide range of temperature and pressure conditions. For this reason chlorite minerals are ubiquitous minerals within low and medium temperature metamorphic rocks, some igneous rocks, hydrothermal rocks and deeply buried sediments.

The name chlorite is from the Greek chloros (χλωρός), meaning "green", in reference to its color. They do not contain the element chlorine, also named from the same Greek root.

The typical general formula is: (Mg,Fe)3(Si,Al)4O10(OH)2·(Mg,Fe)3(OH)6. This formula emphasizes the structure of the group.

Chlorites have a 2:1 sandwich structure (2:1 sandwich layer = tetrahedral-octahedral-tetrahedral = t-o-t...), this is often referred to as a talc layer. Unlike other 2:1 clay minerals, a chlorite's interlayer space (the space between each 2:1 sandwich filled by a cation) is composed of (Mg2+, Fe3+)(OH)6. This (Mg2+, Fe3+)(OH)6 unit is more commonly referred to as the brucite-like layer, due to its closer resemblance to the mineral brucite (Mg(OH)2). Therefore, chlorite's structure appears as follows:

That's why they are also called 2:1:1 minerals.

This page was last edited on 2 April 2018, at 03:55 (UTC).
Reference: under CC BY-SA license.

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